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dc.title | Photodegradation of isotactic poly(1-butene): Multiscale characterization | en |
dc.contributor.author | Beníček, Lubomír | |
dc.contributor.author | Chvátalová, Lenka | |
dc.contributor.author | Obadal, Martin | |
dc.contributor.author | Čermák, Roman | |
dc.contributor.author | Verney, Vincent | |
dc.contributor.author | Commereuc, Sophie | |
dc.relation.ispartof | Polymer Degradation and Stability | |
dc.identifier.issn | 0141-3910 Scopus Sources, Sherpa/RoMEO, JCR | |
dc.date.issued | 2011 | |
utb.relation.volume | 96 | |
utb.relation.issue | 10 | |
dc.citation.spage | 1740 | |
dc.citation.epage | 1744 | |
dc.type | article | |
dc.language.iso | en | |
dc.publisher | Elsevier | en |
dc.identifier.doi | 10.1016/j.polymdegradstab.2011.08.001 | |
dc.relation.uri | https://www.sciencedirect.com/science/article/pii/S0141391011002709 | |
dc.subject | infrared spectroscopy | en |
dc.subject | isotactic poly(1-butene) | en |
dc.subject | photodegradation | en |
dc.subject | rheology | en |
dc.subject | thermal behaviour | en |
dc.description.abstract | The effect of photodegradation in isotactic poly(1-butene) (PB-1) have been investigated using rheology, differential scanning calorimetry and infrared spectroscopy. Two commercially available grades of PB-1 with different average molecular weight were chosen. Specimens prepared by compression moulding were UV irradiated in the interval from 0 to 70 h. UV-induced changes in molecular structure have been followed by evolution of rheological properties, thermal properties and degradation by-products. Thermal analysis showed significant changes in crystallization behaviour influencing morphology and resulting thermal properties. Moreover it has been confirmed that the degradation significantly retards the phase transformation. Rheological measurement has been found as an effective method for determination of early stages of photodegradation of PB-1. © 2011 Elsevier Ltd. All rights reserved. | en |
utb.faculty | Faculty of Technology | |
utb.faculty | University Institute | |
dc.identifier.uri | http://hdl.handle.net/10563/1002641 | |
utb.identifier.rivid | RIV/70883521:28110/11:43865627!RIV12-MSM-28110___ | |
utb.identifier.rivid | RIV/70883521:28610/11:43865627!RIV12-MSM-28610___ | |
utb.identifier.obdid | 43865641 | |
utb.identifier.scopus | 2-s2.0-80052430702 | |
utb.identifier.wok | 000295501000005 | |
utb.identifier.coden | PDSTD | |
utb.source | j-scopus | |
dc.date.accessioned | 2012-02-10T13:15:22Z | |
dc.date.available | 2012-02-10T13:15:22Z | |
utb.ou | Centre of Polymer Systems | |
utb.contributor.internalauthor | Beníček, Lubomír | |
utb.contributor.internalauthor | Chvátalová, Lenka | |
utb.contributor.internalauthor | Čermák, Roman | |
utb.fulltext.affiliation | Lubomír Beníček a,b,*, Lenka Chvátalová a , Martin Obadal c, Roman Čermák a,b,Vincent Verney d,e, Sophie Commereuc d,f a Tomas Bata University in Zlin, Faculty of Technology, Department of Polymer Engineering, nam. T.G.Masaryka 275, 762 72 Zlin, Czech Republic b Tomas Bata University in Zlin, University Institute, Centre of Polymer Systems, Nad Ovcirnou 3685, 760 01 Zlin, Czech Republic c Borealis Polyolefine GmbH, St.-Peter-Strasse 25, 4021 Linz, Austria d Clermont Universite, Université Blaise Pascal, LPMM, BP 10448, F-63000 Clermont-Ferrand, France e CNRS, UMR 6505, LPMM, F-63177 Aubiere Cedex, France f Clermont Universite, ENSCCF, LPMM, BP 10448, F-63000 Clermont-Ferrand, France | |
utb.fulltext.dates | Received 30 May 2011 Received in revised form 29 July 2011 Accepted 2 August 2011 Available online 7 August 2011 | |
utb.fulltext.sponsorship | The paper was supported by the Operational Programme Research and Development for Innovations co-funded by the European Regional Development Fund (ERDF) and national budget of Czech Republic within the framework of the Centre of Polymer Systems project (reg. number: CZ.1.05/2.1.00/03.0111). The authors also kindly acknowledge the support provided by the Ministry of Education, Youth and Sport of the Czech Republic (project MSM7088352101). | |
utb.fulltext.projects | CZ.1.05/2.1.00/03.0111 | |
utb.fulltext.projects | MSM7088352101 | |
utb.fulltext.faculty | Faculty of Technology | |
utb.fulltext.ou | Department of Polymer Engineering |