Impact of grain size and structural changes on magnetic, dielectric, electrical, impedance and modulus spectroscopic characteristics of CoFe2O4 nanoparticles synthesized by honey mediated sol-gel combustion method

Yadav, Raghvendra Singh; Kuřitka, Ivo; Vilčáková, Jarmila; Havlica, Jaromír; Másilko, Jiří; Kalina, Lukáš; Tkacz, Jakub; Švec, Jiří; Enev, Vojtěch; Hajdúchová, Miroslava

dc.title	Impact of grain size and structural changes on magnetic, dielectric, electrical, impedance and modulus spectroscopic characteristics of CoFe2O4 nanoparticles synthesized by honey mediated sol-gel combustion method	en
dc.contributor.author	Yadav, Raghvendra Singh
dc.contributor.author	Kuřitka, Ivo
dc.contributor.author	Vilčáková, Jarmila
dc.contributor.author	Havlica, Jaromír
dc.contributor.author	Másilko, Jiří
dc.contributor.author	Kalina, Lukáš
dc.contributor.author	Tkacz, Jakub
dc.contributor.author	Švec, Jiří
dc.contributor.author	Enev, Vojtěch
dc.contributor.author	Hajdúchová, Miroslava
dc.relation.ispartof	Advances in Natural Sciences: Nanoscience and Nanotechnology
dc.identifier.issn	2043-6254 Scopus Sources, Sherpa/RoMEO, JCR
dc.identifier.issn	2043-6262 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued	2017
utb.relation.volume	8
utb.relation.issue	4
dc.type	article
dc.language.iso	en
dc.publisher	Institute of Physics Publishing
dc.identifier.doi	10.1088/2043-6254/aa853a
dc.relation.uri	http://iopscience.iop.org/article/10.1088/2043-6254/aa853a/meta
dc.subject	autoclaving techniqueconventional heating	en
dc.subject	gold nanoparticles-hydrothermal	en
dc.subject	gold nanoparticles-hydrothermal autoclaving technique-conventional heating technique-catalytic activity	en
dc.subject	technique-catalytic activity	en
dc.description.abstract	In this work CoFe2O4 spinel ferrite nanoparticles were synthesized by honey mediated sol-gel combustion method and further annealed at higher temperature 500 °C, 700 °C, 900 °C and 1100 °C. The synthesized spinel ferrite nanoparticles is investigated by x-ray diffraction, Raman spectroscopy, Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis/differential scanning calorimetry (TGA/DSC), field emission scanning electron microscopy, x-ray photoelectron spectroscopy and vibrating sample magnetometer. The x-ray diffraction study reveals face-centered cubic spinel cobalt ferrite crystal phase formation. The crystallite size and lattice parameter are increased with annealing temperature. Raman and Fourier transform infrared spectra also confirm spinel ferrite crystal structure of synthesized nanoparticles. The existence of cation at octahedral and tetrahedral site in cobalt ferrite nanoparticles is confirmed by x-ray photoelectron spectroscopy. Magnetic measurement shows increased saturation magnetization 74.4 emu g-1at higher annealing temperature 1100 °C, high coercivity 1347.3 Oe at lower annealing temperature 500 °C, and high remanent magnetization 32.3 emu g-1at 900 °C annealing temperature. The magnetic properties of synthesized ferrite nanoparticles can be tuned by adjusting sizes through annealing temperature. Furthermore, the dielectric constant and ac conductivity shows variation with frequency (1-107Hz), grain size and cation redistribution. The modulus spectroscopy study reveals the role of bulk grain and grain boundary towards the resistance and capacitance. The cole-cole plots in modulus formalism also well support the electrical response of nanoparticles originated from both grain and grain boundaries. The dielectric, electrical, magnetic, impedance and modulus spectroscopic characteristics of synthesized CoFe2O4spinel ferrite nanoparticles demonstrate the applicability of these nanoparticles for magnetic recording, memory devices and for microwave applications.	en
utb.faculty	University Institute
dc.identifier.uri	http://hdl.handle.net/10563/1007682
utb.identifier.obdid	43877130
utb.identifier.scopus	2-s2.0-85039073109
utb.identifier.wok	000980804500003
utb.source	j-scopus
dc.date.accessioned	2018-01-15T16:31:39Z
dc.date.available	2018-01-15T16:31:39Z
dc.description.sponsorship	LO1504, NPU, Northwestern Polytechnical University
dc.description.sponsorship	Ministry of Education, Youth and Sports of the Czech Republic-Program NPU I [LO1504]
dc.rights	Attribution 3.0 International
dc.rights.uri	https://creativecommons.org/licenses/by/3.0/
dc.rights.access	openAccess
utb.ou	Centre of Polymer Systems
utb.contributor.internalauthor	Yadav, Raghvendra Singh
utb.contributor.internalauthor	Kuřitka, Ivo
utb.contributor.internalauthor	Vilčáková, Jarmila
utb.fulltext.affiliation	Raghvendra Singh Yadav1, Ivo Kuřitka1, Jarmila Vilcakova1, Jaromir Havlica2, Jiri Masilko2, Lukas Kalina2, Jakub Tkacz2, Jiří Švec2, Vojtěch Enev2 and Miroslava Hajdúchová2 1 Centre of Polymer Systems, University Institute, Tomas Bata University in Zlín, Trida Tomase Bati 5678, 760 01 Zlín, Czechia 2 Materials Research Centre, Brno University of Technology, Purkyňova 464/118, 61200 Brno, Czechia E-mail: yadav@cps.utb.cz
utb.fulltext.dates	Received 9 February 2017 Accepted for publication 26 July 2017 Published 29 August 2017
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utb.fulltext.sponsorship	This work was supported by the Ministry of Education, Youth and Sports of the Czech Republic—Program NPU I (LO1504).
utb.wos.affiliation	[Yadav, Raghvendra Singh; Kuritka, Ivo; Vilcakova, Jarmila] Tomas Bata Univ Zlin, Univ Inst, Ctr Polymer Syst, Trida Tomase Bati 5678, Zlin 76001, Czech Republic; [Havlica, Jaromir; Masilko, Jiri; Kalina, Lukas; Tkacz, Jakub; Svec, Jiri; Enev, Vojtech; Hajduchova, Miroslava] Brno Univ Technol, Mat Res Ctr, Purkynova 464-118, Brno 61200, Czech Republic
utb.scopus.affiliation	Centre of Polymer Systems, University Institute, Tomas Bata University in Zlín, Trida Tomase Bati 5678, Zlín, Czech Republic; Materials Research Centre, Brno University of Technology, Purkyňova 464/118, Czechia, Brno, Czech Republic
utb.fulltext.projects	LO1504