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Název: | Hierarchical PANI/NiCo-LDH core-shell composite networks on carbon cloth for high performance asymmetric supercapacitor | ||||||||||
Autor: | Ge, Xinjin; He, Ying; Plachý, Tomáš; Kazantseva, Natalia E.; Sáha, Petr; Cheng, Qilin | ||||||||||
Typ dokumentu: | Recenzovaný odborný článek (English) | ||||||||||
Zdrojový dok.: | Nanomaterials. 2019, vol. 9, issue 4 | ||||||||||
ISSN: | 2079-4991 (Sherpa/RoMEO, JCR) | ||||||||||
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DOI: | https://doi.org/10.3390/nano9040527 | ||||||||||
Abstrakt: | In this work, a facile two-step strategy is adopted to construct hierarchical polyaniline/ NiCo-layered double hydroxide (PANI/NiCo-LDH) core-shell composite nanofiber networks on carbon cloth (CC). Three-dimensional (3D) porous PANI nanofiber networks are firstly uniformly anchored on CC by in-situ oxidative polymerization, followed by growth of NiCo-LDH nanoflakes on the crosslinked PANI framework via electrochemical deposition. The morphology and electrochemical properties of PANI/NiCo-LDH composites are controlled by the deposition time of LDH. Benefiting from rapid electron transport and ion diffusion, the well-defined PANI/NiCo-LDH hierarchical composite with 200 s deposition of LDH delivers a large capacitance of 1845 F g -1 at 0.5 A g -1 and excellent cycling stability of 82% capacitance retention after 5000 cycles at a very high current density of 10.0 A g -1 . Furthermore, an asymmetric supercapacitor (ASC) assembled with PANI/NiCo-LDH as a positive electrode and activated carbon (AC) as a negative electrode exhibits a high capacitance of 147.2 F g -1 in a potential range from 0 to 1.5 V and superior energy density of 46.0 Wh kg -1 at a power density of 351.6W kg -1 . © 2019 by the authors. Licensee MDPI, Basel, Switzerland. | ||||||||||
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