Imprinting of different types of graphene oxide with metal cations

Zabierowski, Piotr Wladyslaw; Osička, Josef; Šťastný, Josef; Filip, Jaroslav

dc.title	Imprinting of different types of graphene oxide with metal cations	en
dc.contributor.author	Zabierowski, Piotr Wladyslaw
dc.contributor.author	Osička, Josef
dc.contributor.author	Šťastný, Josef
dc.contributor.author	Filip, Jaroslav
dc.relation.ispartof	Electrochimica Acta
dc.identifier.issn	0013-4686 Scopus Sources, Sherpa/RoMEO, JCR
dc.identifier.issn	1873-3859 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued	2022
utb.relation.volume	434
dc.type	article
dc.language.iso	en
dc.publisher	Pergamon-Elsevier Science Ltd
dc.identifier.doi	10.1016/j.electacta.2022.141307
dc.relation.uri	https://www.sciencedirect.com/science/article/pii/S0013468622014645
dc.relation.uri	https://www.sciencedirect.com/science/article/pii/S0013468622014645/pdfft?md5=e9f0e3f3f56b0c87fed7da2b9f6b14dd&pid=1-s2.0-S0013468622014645-main.pdf
dc.subject	graphene oxide	en
dc.subject	metal cations	en
dc.subject	electrochemical determination	en
dc.subject	toxic metals	en
dc.subject	ion imprinting	en
dc.description.abstract	It is known that graphene oxide (GO) particles bear negatively charged oxygen moieties which can interact with cations, what has been several times employed in fabrication of electrochemical sensors for metals. In this work, for the first time GO was treated with Cu2+, Cd2+ or Pb2+ cations in a way similar to the ion imprinting by simple incubation of the two components and the synthesized nanomaterials were then deposited on carbon electrode surface forming electrochemical sensors towards lead cations. It was found that simple filtration of GO is very efficient way for collection of GO particles that could be imprinted most efficiently in terms of high electrochemical response towards lead cations. Part of the success also lies in high redox potential of Cu2+ that turned to be the best choice for the GO imprinting. It was also proven that the electrodes modified with ion-imprinted GO could work as the sensors of Pb2+ in drop amount of solution as well as they provide stable response under flowthrough cell conditions suitable, for example, for online monitoring of water quality.	en
utb.faculty	Faculty of Technology
utb.faculty	University Institute
dc.identifier.uri	http://hdl.handle.net/10563/1011182
utb.identifier.obdid	43883974
utb.identifier.scopus	2-s2.0-85139876760
utb.identifier.wok	000930651800007
utb.identifier.coden	ELCAA
utb.source	j-scopus
dc.date.accessioned	2022-10-26T13:40:45Z
dc.date.available	2022-10-26T13:40:45Z
dc.description.sponsorship	Grantová Agentura České Republiky, GA ČR: GAČR 20–27735Y
dc.description.sponsorship	Czech science foundation [GA.CR 20-27735Y]
dc.description.sponsorship	Czech science foundation [GAC ?, R 20 - 27735Y]
utb.ou	Department of Environmental Protection Engineering
utb.ou	Centre of Polymer Systems
utb.contributor.internalauthor	Zabierowski, Piotr Wladyslaw
utb.contributor.internalauthor	Osička, Josef
utb.contributor.internalauthor	Šťastný, Josef
utb.contributor.internalauthor	Filip, Jaroslav
utb.fulltext.affiliation	Piotr Zabierowski a,b, Josef Osička c, Josef Šťastný a, Jaroslav Filip a,* a Department of Environmental Protection Engineering, Faculty of Technology, Tomas Bata University in Zlin, Nad Ovcirnou 3685, Zlin 760 01, Czech Republic b CNR – Istituto per i Processi Chimico-Fisici, Sezione di Bari, via E. Orabona, 4, Bari 70126, Italy c Centre of Polymer Systems, Tomas Bata University in Zlin, Trida Tomase Bati 5678, Zlin 760 01, Czech Republic * Corresponding author. E-mail address: jfilip@utb.cz (J. Filip).
utb.fulltext.dates	Received 9 August 2022 Received in revised form 3 October 2022 Accepted 5 October 2022 Available online 6 October 2022
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utb.fulltext.sponsorship	This work was supported by Czech science foundation [grant number GAČR 20–27735Y].
utb.wos.affiliation	[Zabierowski, Piotr; Stastny, Josef; Filip, Jaroslav] Tomas Bata Univ Zlin, Fac Technol, Dept Environm Protect Engn, Nad Ovcirnou 3685, Zlin 76001, Czech Republic; [Zabierowski, Piotr] CNR, Sez Bari, Ist Proc Chim Fis, Via E Orabona 4, I-70126 Bari, Italy; [Osicka, Josef] Tomas Bata Univ Zlin, Ctr Polymer Syst, Trida Tomase Bati 5678, Zlin 76001, Czech Republic
utb.scopus.affiliation	Department of Environmental Protection Engineering, Faculty of Technology, Tomas Bata University in Zlin, Nad Ovcirnou 3685, Zlin, 760 01, Czech Republic; CNR – Istituto per i Processi Chimico-Fisici, Sezione di Bari, via E. Orabona, 4, Bari, 70126, Italy; Centre of Polymer Systems, Tomas Bata University in Zlin, Trida Tomase Bati 5678, Zlin, 760 01, Czech Republic
utb.fulltext.projects	GAČR 20–27735Y
utb.fulltext.faculty	Faculty of Technology
utb.fulltext.ou	Department of Environmental Protection Engineering