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Název: | 1-methyl-3-phenyl-3-thiocyanato-1H,3H-quinoline-2,4-dione: A novel thiocyanating agent | ||||||||||
Autor: | Klásek, Antonín; Mrkvička, Vladimír | ||||||||||
Typ dokumentu: | Recenzovaný odborný článek (English) | ||||||||||
Zdrojový dok.: | Journal of Heterocyclic Chemistry. 2003, vol. 40, issue 5, p. 747-752 | ||||||||||
ISSN: | 0022-152X (Sherpa/RoMEO, JCR) | ||||||||||
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DOI: | https://doi.org/10.1002/jhet.5570400501 | ||||||||||
Abstrakt: | Under mild reaction conditions, the thiocyanato group is selectively transferred from 1-methyl-3-phenyl-3-thiocyanato-1H,3H-quinoline-2,4-dione (3) to some nucleophiles. Aliphatic primary and secondary amines are converted to S-cyanothiohydroxylamines, anilines afford p-thiocyanatoanilines, Wittig reagent is thiocyanated in ?-position, and thiols are oxidized to disulfides. | ||||||||||
Plný text: | http://onlinelibrary.wiley.com/doi/10.1002/jhet.5570400501/abstract | ||||||||||
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