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Title: | Note on the relation betweeen the parameters of the Mark-Houwink-Kuhn-Sakurada equation | ||||||||||
Author: | Halabalová, Věra; Šimek, Lubomír; Dostál, Jiří; Bohdanecký, Miloslav | ||||||||||
Document type: | Peer-reviewed article (English) | ||||||||||
Source document: | International Journal of Polymer Analysis and Characterization. 2004, vol. 9, issue 1-3, p. 65-75 | ||||||||||
ISSN: | 1023-666X (Sherpa/RoMEO, JCR) | ||||||||||
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DOI: | https://doi.org/10.1080/10236660490890484 | ||||||||||
Abstract: | The relation between the parameters K and a of the equation [eta] = Km(a). which has been empirically established by several authors,, is discussed. Equations describing this relation are derived based on the two-parameter theory of the intrinsic viscosity for flexible, chain polymers (where a < 0.8) and on the worm-like cylinder model for stiff chains (a > 0.8). The correspondence of calculated and empirical results is good. | ||||||||||
Full text: | http://www.tandfonline.com/doi/abs/10.1080/10236660490890484 | ||||||||||
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