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Title: | Determination of intrinsic binding modes by mass spectrometry: Gas-phase behavior of adamantylated bisimidazolium guests complexed to cucurbiturils | ||||||||||
Author: | Černochová, Jarmila; Branná, Petra; Rouchal, Michal; Kulhánek, Petr; Kuřitka, Ivo; Vícha, Robert | ||||||||||
Document type: | Peer-reviewed article (English) | ||||||||||
Source document: | Chemistry - A European Journal. 2012, vol. 18, issue 43, p. 13633-13637 | ||||||||||
ISSN: | 0947-6539 (Sherpa/RoMEO, JCR) | ||||||||||
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DOI: | https://doi.org/10.1002/chem.201201444 | ||||||||||
Abstract: | Adamantylated bisimidazolium cations exhibit a distinct fragmentation pathway in contrast to their cucurbit[7]uril (CB7) complexes (see scheme). The observed alternative fragmentation of the guest molecule in a complex clearly correlates to the supposed sterically hindered or allowed slippage of the macrocycle over the axel molecule. | ||||||||||
Full text: | http://onlinelibrary.wiley.com/doi/10.1002/chem.201201444/abstract | ||||||||||
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